I had seen some similar issues with Windows 7 and smb-Folders complete unrelated to Geany. For some reason -- i didn't investigate more at this time and don't have access to this setup anymore -- I wasn't able to run some installer or general executables from mounted device. My idea was it might be related to some issue with antivirus. To solve it I needed to copy file to local file system. Maybe worth double checking before deep digging into Geany.

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